The heat pipe is hollow with the space inside evacuated, much the same as the solar tube. In this case insulation is not the goal, but rather to alter the state of the liquid inside. Inside the heat pipe is a small quantity of purified water and some special additives. At sea level water boils at 100oC (212oF), but if you climb to the top of a mountain the boiling temperature will be less that 100oC (212oF). This is due to the difference in air pressure.
Based on this principle of water boiling at a lower temperature with decreased air pressure, by evacuating the heat pipe, we can achieve the same result. The heat pipes used in solar collectors have a boiling point of only 30oC (86oF). So when the heat pipe is heated above 30oC (86oF) the water vaporizes. This vapor rapidly rises to the top of the heat pipe transferring heat. As the heat is lost at the condenser (top), the vapor condenses to form a liquid (water) and returns to the bottom of the heat pipe to once again repeat the process.
At room temperature the water forms a small ball, much like mercury does when poured out on a flat surface at room temperature. When the heat pipe is shaken, the ball of water can be heard rattling inside. Although it is just water, it sounds like a piece of metal rattling inside.
This explanation makes heat pipes sound very simple. A hollow copper pipe with a little bit of water inside, and the air sucked out! Correct, but in order to achieve this result more than 20 manufacturing procedures are required and with strict quality control.
Material quality and cleaning is extremely important to the creation of a good quality heat pipe. If there are any impurities inside the heat pipe it will effect the performance. The purity of the copper itself must also be very high, containing only trace amounts of oxygen and other elements.
Often heat pipes use a wick or capillary system to aid the flow of the liquid, but for the heat pipes used in solar collectors no such system is required as the interior surface of the copper is extremely smooth, allowing efficient flow of the liquid back to the bottom. Also heat pipes are not installed horizontally. Heat pipes can be designed to transfer heat horizontally, but the cost is much higher.
Even though the heat pipe is a vacuum and the boiling point has been reduced to only 25-30oC (86oF), the freezing point is still the same as water at sea level, 0oC (32oF). Because the heat pipe is located within the evacuated glass tube, brief overnight temperatures as low as -20oC (14oF) will not cause the heat pipe to freeze. Plain water heat pipes will be damaged by repeated freezing. The water used in heat pipes still freezes in cold conditions, but it freezes in a controlled way that does not cause swelling of the copper pipe.